Bis(μ-N-nitroso-N-phenylhydroxylaminato)-κ3 O,O′:O′;κ3 O′:O,O′-bis[(N-nitroso-N-phenylhydroxylaminato-κ2 O,O′)lead(II)]
نویسندگان
چکیده
The four cupferronate ions in the dinuclear title compound, [Pb(2)(C(6)H(5)N(2)O(2))(4)], O,O'-chelate to the two Pb(II) atoms; two of the four nitroso O atoms are also involved in bridging. The geometry of both five-coordinate Pb(II)atoms is distorted Ψ-octa-hedral; if another two longer inter-molecular Pb⋯O inter-actions [at 2.955 (1) and 3.099 (1) Å] are considered, the geometry is a distorted Ψ-square anti-prism.
منابع مشابه
A second triclinic polymorph of bis(μ-N-nitroso-N-phenylhydroxylaminato)-κ3 O,O′:O′;κ3 O′:O,O′-bis[(N-nitroso-N-phenylhydroxylaminato-κ2 O,O′)lead(II)]
The cupferronate ions in the centrosymmetric dinuclear title compound, [Pb(2)(C(6)H(5)N(2)O(2))(4)], O,O'-chelate to the two Pb(II) atoms; two of the four nitroso O atoms are also involved in bridging. The geometries of the five-coordinate Pb(II) atoms in the two independent mol-ecules are Ψ-octa-hedral; if more remote Pb⋯O inter-actions are also considered, the coordination number is increased...
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